Antioxidant 1790

 

CAS NO.: 40601-76-1

 

Chemical Name: 

tris(4-tert-butyl-3-hydroxy-2,6-dimethyl-benzyl);Tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate; Antioxidant 1790; Cyanox 1790; Irganox 3790; Primanox1790; DEOX-1790; 1,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione; 1,3,5-Tris(4-tert-butyl-3-hydroxy-2,6-dimethyl benzyl)–1,3,5-triazine-2,4,6-(1H,3H,5H)-trione; Antioxidant-1790 ; ,3,5-tris(4-tert-butyl-3-hydroxy-2,6-dimethylbenzyl)-1,3,5-triazinane-2,4,6-trione; Thanox 1790; Irganox 1790; 

,3,5-Tris-(4-tert-butyl-2,6-dimethyl-3-hydroxybenzyl)-isocyanurate;

 

Formula: C42H57N3O6 

 

Molecular Weight: 700

 

Chemical Structure:

 

 

Specification:

Item	Standard
Appearance	White to off-white powder
Purity	≥95%
Ash	≤0.1%
Volatile	≤0.5%
Melting point	158℃~162℃
Color AHPA	≤133

 

Applications:

Antioxidant 1790 is a kind of hindered phenol primary antioxidant.

①　Antioxidant 1790 can be used in polypropylene

②　Antioxidant 1790 can be used in polyethylene(PE)

③　Antioxidant 1790 can be used in polyamide

④　Antioxidant 1790 can be used in ABS resin

⑤　Antioxidant 1790 can be used in polystyrene

⑥　Antioxidant 1790 can be used in polyester

⑦　Antioxidant 1790 can be used in fiber resin

⑧　Antioxidant 1790 can be used in elastic fiber

⑨　Antioxidant 1790 can be used in PE PP food package as USA FDA regulation

 

advantages:

①　Low dosage and excellent performance: only with 0.02%~0.1% addition can effectively prevent goods from heat and oxidization degradation during the usage and high temperature processing 

②　Great synergy with some secondary antioxidants such as phosphite ester and thiodipropionate type.

③　Geat boiling water resistance ability

①　Good resistance to extraction of the detergent cleaning 

 

Package and storage: 

40kgs/paper drum 

Or as customer’s request

Stock it in well-ventilation cool, dry area. 

 

Transportation: 

Antioxidant 1790 is not a dangerous goods according to transportation regulation

 

Shelf life:

2 years if stock as above conditions

Antioxidant 1520

 

CAS NO.: 110553-27-0 

 

Synonym: 

4,6-bis(octylthiomethyl)-o-cresol;2-Methyl-4,6-bis(octylsulfanylmethyl)phenol  

2-methyl-4,6-bis(octylsulfanylmethyl)phenol 4,6-bis (octylthiomethyl)-o-cresol; Phenol, 2-methyl-4,6-bis(octylthio)methyl-; 2,4-BIS(OCTYLTHIOMETHYL)-6-METHYLPHENOL; 2-METHYL-4,6-BIS((OCTYLTHIO)METHYL)PHENOL; Irganox 1520; Primanox1520; Antioxidant 1520

 

Formula: C25H44OS2

 

Molecular Weight: 424.7  

 

Chemical Structure:

 

 

Specification:

Item	Standard
Appearance	Low viscosity pale yellow liquid
Purity	≥96%
Transmittance @ 425nm	≥97%
Transmittance after NaOMe @ 425nm	≥95%
Melting point	14℃
Flash point	>200℃
Density @ 20℃	0.98
Viscosity @ 20℃	85~90mPa.s
Solubility @ 20℃ as following
Water	≤0.1%
Ethanol	＞50%
Acetone	＞50%
Chloroform	＞50%
Ethyl acetate	＞50%
N-hexane	＞50%
Methanol	＞50%
Toluene	＞50%

 

 Application: 

Antioxidant 1520 is a new kind multifunctional liquid phenolic antioxidant with highly effective stabilization for organic materials such as elastomers, plastics, adhesives sealants, oils and lubricants.as there are 2,4  thioether substitutional groups, antioxidant 1520 both can act as primary and also secondary antioxidant.   

①　Antioxidant 1520 can protects above materials against thermo-oxidative degradation.  

②　Antioxidant 1520 can be applied for emulsion and solution polymerized elastomers such as BR, SBR, NBR, SBS, and others. 

③　Antioxidant 1520  is effective both as a raw elastomer and compound stabilizer.  

④　Antioxidant 1520 also has perfect performance in lubricant,various adhesive, sealant, and latex applications. But  It is not recommended for odor sensitive hot melt adhesives or their raw materials. 

⑤　Antioxidant 1520 can be used alone at low levels without co-stabilizers to provide both processing and long-terms heat aging stability. If needed, it also can be used with other additives such as secondary antioxidants(antioxidant 264,),metal passivator agent, phosphite ester;phosphate ester;peroxide remover;amid stabilizer;alkaline co-stabilizers;Nucleating agents;benzofuranone, light stabilizers, and other functional stabilizers.  The effectiveness of this product used in a wide range of 

elastomers is exceptional along with extensive food contact approvals. 

 

Advantages:

①　Non-discoloring, non-staining

②　Stable to light and heat 

③　Environment friendly

④　Low in volatility

⑤　Good compatibility with many other raw materials

⑥　Low dosage(0.1%~0.3%) but better performance compared with traditional antioxidant series(0.5%~1%) 

 

Package and storage: 

200kgs/galvanized /iron drum 

or as customer’s request;

Stock it in well-ventilation cool, dry area. 

 

Transportation: 

Antioxidant 1520 is not a dangerous goods according to transportation regulation

 

Shelf life:

2 years if stock as above conditions

Antioxidant 1081

 

Equivalent to: Ciba SC Inganox 1081;Great Lakes Lowinox TBP-6

 

CAS NO.: 90-66-4

 

Synonym:   

IRGANOX 1081

Antioxidant 2246-S

2,2′-thiobis(6-tert-butyl-p-cresol)

6,6′-di-tert-butyl-2,2′-thiodi-p-cresol

3-tert-Butyl-2-hydroxy-5-methylphenyl sulfide

ANTIOXIDANT LK-1081

2.2′-Thio Bis(6-Tert-Butyl-4-Methylphenol)

Phenol, 2,2-thiobis6-(1,1-dimethylethyl)-4-methyl-

6,6′-Di-tert.-butyl-2,2′-thiodi-p-kresol

2,2’-thiobis(6-t-butyl-4-methylphenol

2,2′- THIO-BIS (4-METHY-6-PHENOE)

ANTIOXIDANTLK-10812,2-THIO-BIS(4-METHY-6-TERT-BUTYL-PHENOL)

2,2”- THIO-BIS(4-METHY-6-N-BUTYL- PHENOL)

2,2′-Thiobis[6-(1,1-dimethylethyl)-4-methylphenol]

6,6′-Thiobis(2-tert-butyl-4-methylphenol)

Advastab-406

CAO-6

2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methyl-phenyl)sulfanyl-4-methyl-phenol

2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol

2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methyl-phenyl)thio]-4-methyl-phenol

 

 

Formula: C22H30O2S

 

Molecular Weight: 358.5374

 

Chemical Structure:

 

 

 

 

Specification:

Item	Standard
Appearance	White to off-white powder
Purity	≥99%
Melting area	81℃~86℃
Volatile	≤0.5%
Ash content	≤0.1%

 

 

 

 

 

 

 

 

 

 

 

 

Characteristics: 

Antioxidant 1081 is a very popular phenol antioxidant with excellent performance.it is environment-friendly,nontoxic and without coloration.

 

Applications

①　In rubber industry: antioxidant 1018 is a very good antioxidant for  PE,PP,synthetic rubber and latex.products by adding antioxidant 1081 can resist high temperature,prevent UV absorber,reduce the damage of multiple deformation and can passivate the unstable transition metal salt. These performance is more obvious in dry rubber by adding antioxidant 1081(2246-S) than by antioxidant 2246.antioxidant 1081 is environment-friendly and don’t be decolored by exposing it to the sunlight.it is mainly used in producing white sidewall of tires,other light color goods and latex goods.

②　In plastic industry: antioxidant 1081 can prevent the heat-aging and light-aging of PE,PVC,polyamide,chlorinated polyether,HIPS,ABS resin,daicel,cellulosic resin etc.especially in the processing of polyamine hot melt adhesive,antioxidant is a very important choice as the main antioxidant.when it is used with phosphite ester assistant antioxidant there is a very good synergistic effect which is much better by using them alone.

③　In oil industry: antioxidant 1081 is an excellent stabilization agent for lubricant,blend diesel fuel,gas oil,engine oil,anti-wear hydraulic fluid.it can prevent these oils from heat-aging and light-aging and inhibit nitryl oxidation.because of the good synergistic effect of S and phenol antioxidant 1081 has good oil solubility.this make it easy and convenient add into these different oils.the comprehensive performance of antioxidant is much better than common kind antioxidant such as T501,L135,L115,DNA,AP-36 and especially suitable for hydrotreated base oil and lubricant.the dosage is just 1/2 of those common antioxidant such as T501.but the final effect is far better than T501.it can improve the quality and level of the finished goods easily and greatly.

①　synergistic effect: sulfur-containing hindered phenol antioxidant 1081 is rarely absorbed by the carbon black but has very obvious synergistic effect as when it is used together with carbon black as they are transferred into chemical compounds with greater antioxidant efficacy under the catalysis of carbon black that enhances stability of the polymer.antioxidant 1081 also has good synergistic effect with alkyl phenol or phosphite compounds also.it works very well when used in producing high electrical property plastics.general dosage is 0.1~1 phr.

 

 

Package and storage: 

20kgs or 25kgs/paper drum

or as customer’s request;

Stock in well-ventilation cool, dry area.

 

 

Transportation:

Antioxidant 1081 is not a dangerous goods according to transportation regulation

 

 

Shelf life:

2 years if stock as above conditions

 

Vulcanization agent 4,4′-Dithiodimorpholine (DTDM)

 

CAS NO.:103-34-4

 

Formula:C8H16N2O2S2

 

Molecular Weight:236.35

 

 

Synonym:morpholine disulfide;4,4′-Dithiodimorpholin;SULFASAN(R) R;Morpholine N,N’-disulfide;N,N’-DIMORPHOLINE DISULFIDE;N,N’-DITHIOBIS(MORPHOLINE);VANAX A;

VANAX A FINE GRIND;VANAX A RODFORM;4,4′-DITHIODIMORPHOLINE

 

 

Chemical Structure:

 

 

 

Specification:

Item	Specification
Appearance	white or light yellow crystal powder
Melting point	≥ 120℃
Heat loss	≤ 0.3%
Ash	≤ 0.3%

 

Application and characteristics:

It is mainly used as vulcanized agent and accelerator for natural rubber and artificial rubber. Under vulcanizing temperature, it can decompose active sulfur, whose content is 27%. In cross linking reaction, it mainly forms monosulphur bond. Its usual use level is 0.5-2 orders. This product, which has the characteristic of processing safely, is usually used together with such accelerators as thiazoles, thiuram, dithiocarbamates etc.

 

Package and storage: 

25kgs/bag or as customer’s request;

 

Storage:

Stock it in well-ventilation cool, dry area.

 

Shelf life:

12 months if stock as above conditions

 

Transportation:

vulcanization agent DTDM is not a dangerous goods according to transportation regulation 

 

 

Vulcanization agent Amylphenol disulfide polymer VA-5

 

Composition: tert-amylphenol disulfide polymer(75% )+silica gel(25%)

 

CAS NO.:68555-98-6

 

Synonym:

Mixture of tert-amylphenol disulfide polymer and silica gel

Amylphenol disulfide polymer;

Arkema Vultac 5 equivalent;

Poly-amylphenol disulfide polymer

Blend- Calcium Silicate, Amyl Disulfide Polymer

Curing Resin
Specification:

Item	Standard	Test Way
Appearance	Beige free flowing powder	Visual
Sulfur content, %	20.0-22.0	Combustion
% Passing 50 Mesh	≥98	/
% Passing 20 Mesh	≥99	/
Water content,%	≤2	/

 

 

Application:

①　Amylphenol disulfide polymer 5is a Sulfur donor for natural and synthetic rubbers.

②　Amylphenol disulfide polymer 5produces a high percentage of mono-sulfidic crosslinks that results in vulcanizates with superior aging characteristics.

③　Amylphenol disulfide polymer 5 can be used as either complete or partial replacements for sulfur and thiuram and DTDM sulfur donors in EV and semi-EV type cure systems.

④　In tires Amylphenol disulfide polymer 5 is used in the inner-liner, chafer,bead apex, sidewalls, and tread.

⑤　Industrial applications include noise damping blocks, motor mounts, dock fenders, elastic threads, automobile engine hoses, gaskets, belts, and other industrial rubber products that require good heat resistance.

⑥　Amylphenol disulfide polymer 5 also aid in rubber processing.

⑦　Amylphenol disulfide polymer 5 polychloroprene vulcanizates have improved flex life.

⑧　Amylphenol disulfide polymer 5 is also an excellent bleaching agent,antioxidant,catalysts in the disproportionation of rosin or rosin esters.

 

Characteristics:

①　Polymers: Natural rubber and synthetic elastomers. Especially good in curing rubber that contains chlorine such as chlorobutyl and polychloroprene.

②　Synergism: Can be used with most typical rubber accelerators and sulfur. When used as a partial replacement for sulfur, Amylphenol disulfide polymer 5 tends to improve dispersion of other additives in the rubber.

③　Crosslink Type: Amylphenol disulfide polymer 5 promotes mono-sulfidic crosslinks resulting in vulcanizates with excellent heat and aging resistance.

④　Non-nitrosamine:Amylphenol disulfide polymer 5 does not produce nitrosamines like many of the other sulfur donors such as DTDM and the thiurams.

 

Advantages:

①　Non-nitrosamine

②　Lower tack to make it easier to stock and handle

③　Lower volatility

④　Lower volatile degradation products

⑤　Good compatibility with many rubber polymers

⑥　Very good antioxidant properties

⑦　Improve heat age properties of vulcanizates because of its generation of mono- and di-sulfic crosslinks

⑧　Increase the resinous plasticizer during processing

⑨　Increase the green tack in NBR,BR and SBR based compounds

⑩　Improve the dispersion of other compound ingredients into rubber

 

Package:

20kgs/paper drum or as customer’s request;

 

Storage: 

It should be stored in dry & cool environment(below 86 °F/30℃) in closed original containers.

 

Shelf Life:

2 years if stored as indicated above

Vulcanization agent Amylphenol disulfide polymer VA-3

 

Composition:Amylphenol disulfide polymer(>95% )+sulfur(<2%)

 

CAS NO.:68555-98-6

 

Synonym:

Amylphenol disulfide polymer;

Arkema Vultac 3 equivalent;

Poly-amylphenol disulfide polymer

Mixture of Phenol, 4-(1,1-dimethylpropyl)-, polymer with sulfur chloride (S2Cl2) with sulfur

Curing Resin
Specification:

Item	Standard	Test Way
Appearance	Reddish-brown to dark brown pastilles	Visual
Sulfur content, %	27.0-29.0	Combustion
Softening point, ℃	78.0-93.0	Ring & Ball
Specific gravity @ 25℃	1.2	Typical
Flash point closed up	644℉(340℃)	/

 

Application:

①　Description:Amylphenol disulfide polymer 3 is nitrosamine-free sulfur donor vulcanizing agent.

②　Polymers: Natural rubber and most synthetic rubbers.

③　Crosslink Type:Amylphenol disulfide polymer 3 produces predominately monosulfide bridges. These bridges are stable and have excellent resistance to heat and ageing when compared with typical polysulfide bridges.

 

Advantages:

①　Non-nitrosamine

②　Lower tack to make it easier to stock and handle

③　Lower volatility

④　Lower volatile degradation products

⑤　Good compatibility with many rubber polymers

⑥　Very good antioxidant properties

⑦　Improve heat age properties of vulcanizates because of its generation of mono- and di-sulfic crosslinks

⑧　Increase the resinous plasticizer during processing

⑨　Increase the green tack in NBR,BR and SBR based compounds

⑩　Improve the dispersion of other compound ingredients into rubber

 

Package:

25kgs/paper drum;25kgs/kraf or as customer’s request;

 

Storage: 

Store it in dry & cool environment(below 86 °F/30℃) in closed original containers.

 

Shelf Life:

2 years if stored as indicated above

Vulcanization agent Alkylphenol disulfide polymer VA-TB7

 

Composition: Para-tert-butylphenol disulfide(> 95 % ) + sulfur(< 3 %) 

 

CAS NO.:60303-68-6

 

Synonym:

Mixture of tert-butylphenol disulfide polymer and sulfur;

Arkema Vultac TB7 equivalent;

Poly-tert-butylphenol disulfide;

Para-tert-butylphenol disulfide polymer;

Alkylphenol disulfide polymer sulfur donor;

Alkylphenol disulfide polymer;

Para-tertiobutylphenol Disulfide Polymer;

Tert-butylphenol disulfide polymer;

Curing Resin

Specification:

Item	Standard	Test Way
Appearance	Yellow to light brown pastilles or powder	Visual
Sulfur content, %	29.5-31.5	Combustion
Softening point, ℃	95-115	Ring & Ball

 

Application: 

①　Alkylphenol disulfide polymer VA-TB7 is a Sulfur donor for natural and synthetic rubbers.

②　Alkylphenol disulfide polymer VA-TB7 produces a high percentage of mono-sulfidic crosslinks that results in vulcanizates with superior aging characteristics.

③　Alkylphenol disulfide polymer VA-TB7 can be used as either complete or partial replacements for sulfur and thiuram and DTDM sulfur donors in EV and semi-EV type cure systems.

④　In tires Alkylphenol disulfide polymer VA-TB7 is used in the inner-liner, chafer,bead apex, sidewalls, and tread.

⑤　Industrial applications include noise damping blocks, motor mounts, dock fenders, elastic threads, automobile engine hoses, gaskets, belts, and other industrial rubber products that require good heat resistance.

⑥　Alkylphenol disulfide polymer VA-TB7 also aid in rubber processing.

⑦　Alkylphenol disulfide polymer VA-TB7 polychloroprene vulcanizates have improved flex life.

⑧　Alkylphenol disulfide polymer VA-TB7 is also an excellent bleaching agent,antioxidant,catalysts in the disproportionation of rosin or rosin esters.

⑨　Alkylphenol disulfide polymer VA-TB7 is a good vulcanizing agent for vegetable oils.

⑩　Dosage: 0.5~20 phr.2 phr is most preferably

 

Characteristics:

①　Polymers: Natural rubber and synthetic elastomers. Especially good in curing rubber that contains chlorine such as chlorobutyl and polychloroprene.

②　Synergism: Can be used with most typical rubber accelerators and sulfur. When used as a partial replacement for sulfur, Alkylphenol disulfide polymer TB7 tends to improve dispersion of other additives in the rubber.

③　Crosslink Type: Alkylphenol disulfide polymer TB7 promotes mono-sulfidic crosslinks resulting in vulcanizates with excellent heat and aging resistance.

④　Non-nitrosamine: Alkylphenol disulfide polymer TB7 does not produce nitrosamines like many of the other sulfur donors such as DTDM and the thiurams.

 

Advantages:

①　Non-nitrosamine

②　Lower tack to make it easier to stock and handle

③　Lower volatility

④　Lower volatile degradation products

⑤　Good compatibility with many rubber polymers

⑥　Very good antioxidant properties

⑦　Improve heat age properties of vulcanizates because of its generation of mono- and di-sulfic crosslinks

⑧　Increase the resinous plasticizer during processing

⑨　Increase the green tack in NBR,BR and SBR based compounds

⑩　Improve the dispersion of other compound ingredients into rubber

 

 

Package:

25kgs/paper drum;25kgs/kraft bag or as customer’s request;

 

Storage: 

It should be stored in dry & cool environment(below 86 °F/30℃) in closed original containers.

 

Shelf Life:

2 years if stored as indicated above